Diverse reactivity of nitrones towards electron deficient acetylenes

Autor:	John P. Rappai, Rakesh Natarajan, Sreedharan Prathapan, Sandhya Radhamani, Peruparampil A. Unnikrishnan
Rok vydání:	2015
Předmět:	Nucleophilic addition Chemistry Materials Chemistry Reactivity (chemistry) General Chemistry Electron Photochemistry Medicinal chemistry Catalysis Cycloaddition Adduct
Zdroj:	New Journal of Chemistry. 39:5580-5588
ISSN:	1369-9261 1144-0546
Popis:	Depending on the nature of N- and C-substituents, nitrones exhibit diverse reactivity towards electron deficient acetylenes. Observed reactions include formal 1,3-dipolar cycloaddition and nucleophilic addition reactions. Possible involvement of zwitterionic intermediates and an unusual 1-aza-Cope rearrangement account for the generation of unexpected 1 : 1 adducts in the reaction of N-arylnitrones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5a61af632af08a821625cac9022137ff https://doi.org/10.1039/c5nj00742a Zobrazit plný text záznamu