Synthesis, X-ray structure and magnetic properties of the apically functionalized monocapped cobalt(ii ) tris-pyridineoximates possessing SMM behaviour
| Autor: | Alexander S. Belov, Svetlana A. Belova, Nikolay N. Efimov, Veronika V. Zlobina, Valentin V. Novikov, Yulya V. Nelyubina, Yan V. Zubavichus, Yan Z. Voloshin, Alexander A. Pavlov |
|---|---|
| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Dalton Transactions. 52:2928-2932 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/d2dt04073e |
| Popis: | Cobalt(ii) pseudoclathrochelates, possessing an intermediate trigonal prismatic–trigonal antiprismatic geometry, exhibit a SMM behaviour with Orbach relaxation barriers ∼ 90 K. NMR experiments confirmed persistence of magnetic characteristics in solution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|