Gold nanoparticle as a Lewis acid catalyst in 1,3-dipolar cycloaddition reaction
| Autor: | Hossein Yazdani, Masood Loni, Ayoob Bazgir, Samira Pardis |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Process Chemistry and Technology Nanoparticle General Chemistry 010402 general chemistry Heterogeneous catalysis 01 natural sciences Catalysis Cycloaddition 0104 chemical sciences Lewis acid catalysis chemistry.chemical_compound chemistry Colloidal gold 1 3-Dipolar cycloaddition Polymer chemistry Oxindole |
| Zdroj: | Catalysis Communications. 134:105844 |
| ISSN: | 1566-7367 |
| DOI: | 10.1016/j.catcom.2019.105844 |
| Popis: | Fe3O4@SiO2@Au nanoparticles were synthesized and characterized by FT-IR, XRD, SEM, AAS, VSM, EDS and XPS measurements. In this study we revealed that gold nanoparticles can act as an efficient catalyst in the regio- and diastereoselective one-pot reactions of aldehydes, dibromoformaldoxime and CH-acids like oxindole or 1,3-indandione. To the best of our knowledge, employing Au-based heterogeneous catalyst for the 1,3-dipolar cycloaddition reaction has not been previously reported. |
| Databáze: | OpenAIRE |
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