Thermal modulation of reaction equilibria controls mass transfer in CO2-binding organic liquids

Autor: Thomas Moore, Anthony J. Varni, Simon H. Pang, Sneha A. Akhade, Sichi Li, Du T. Nguyen, Joshuah K. Stolaroff
Rok vydání: 2023
Předmět:
Zdroj: Energy & Environmental Science. 16:484-490
ISSN: 1754-5706
1754-5692
DOI: 10.1039/d2ee03237f
Popis: CO2BOLs are promising CCS solvents, whose mass transfer rates improve upon cooling. We show this unintuitive behavior is due to slow transport of reaction products from the gas–liquid interface, caused by shifts in reaction equilibria.
Databáze: OpenAIRE