Transfer of Excitation Energy in Solid Solutions of Anthracene‐Polystyrene and 9,10‐Diphenylanthracene‐Polystyrene

Autor:	L. J. Basile, A. Weinreb
Rok vydání:	1960
Předmět:	chemistry.chemical_classification Anthracene Analytical chemistry General Physics and Astronomy 9 10-Diphenylanthracene Polymer Photochemistry Fluorescence Solvent chemistry.chemical_compound chemistry Excited state Radiative transfer Polystyrene Physical and Theoretical Chemistry
Zdroj:	The Journal of Chemical Physics. 33:1028-1036
ISSN:	1089-7690 0021-9606
Popis:	The transfer of excitation energy from the excited solvent to the solute has been studied as a function of solute concentration for solid solutions of anthracene and 9,10‐diphenylanthracene in polystyrene. Transfer efficiencies and fluorescence spectra have been obtained for both systems. The fluorescent light pulse of both systems, when excited by electrons and uv radiation, was recorded and analyzed. Results indicate that radiative transfer predominates at low solute concentration, while at higher solute concentration the transfer process is predominantly nonradiative. Differences between the two systems are probably due to anthracene being chemically bound to the polymer chain while 9,10‐diphenylanthracene is not.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::58daefaac30c36da1fe090108f59b29a https://doi.org/10.1063/1.1731327 Zobrazit plný text záznamu