New Developments in the Synthesis of (E)-8-Styrylflavones

Autor:	Orlando D. C. C. de Azevedo, Artur M. S. Silva, Raquel S. G. R. Seixas
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Chemistry Dimethyl sulfoxide Heck reaction Organic Chemistry Regioselectivity Organic chemistry chemistry.chemical_element Stereoselectivity Palladium Styrene
Zdroj:	Synlett. 26:1379-1384
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0034-1380208
Popis:	A novel route for the synthesis of new (E)-8-styrylflavones is reported. This methodology involves the regio- and stereoselective Heck cross-coupling reaction of 8-iodoflavones and styrene derivatives. The Heck precursors, 8-iodoflavones, were obtained through an efficient regioselective one-pot oxidative cyclization–iodination reaction of (E)-2′-hydroxychalcones by applying the iodine/dimethyl sulfoxide system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::57615f54760b9602f59042bd245ac07b https://doi.org/10.1055/s-0034-1380208 Zobrazit plný text záznamu