CuS nanoparticles-enhanced luminol-O2 chemiluminescence reaction used for determination of paracetamol and vancomycin
| Autor: | Haider A. J. Al Lawati, Mortaza Iranifam, Mahtab Toolooe Gardeh Rasht |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Chemistry
Nanoparticle 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Analytical Chemistry Catalysis law.invention Luminol chemistry.chemical_compound law 0210 nano-technology Instrumentation Spectroscopy Nuclear chemistry Chemiluminescence |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 261:120038 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2021.120038 |
| Popis: | A new chemiluminescence (CL) method was proposed to measure two widely used drugs, including paracetamol (PCM) and vancomycin (VAN). The CL reaction used was the CuS nanoparticles (CuS NPs)-luminol-O2 system. In this system, CuS NPs played the role of catalyst and increased the CL intensity. CuS NPs were easily synthesized by quick-precipitation. CuS NPs were characterized by spectroscopic techniques, and the mean size of NPs was estimated to be about 9 nm. In the developed CL methods, PCM and VAN decreased the CL intensity. In the proposed method, the linear concentration ranges were 4.0 × 10−5–4.0 × 10−4 mol L-1 of PCM and 2.0 × 10−5–6.0 × 10−4 mol L−1 of VAN. The limit of detections were 2.9 × 10-5 mol L-1 and 8.9 × 10-6 mol L-1 for PCM and VAN, respectively. The relative standard deviations (RSD) of the CL method were 2.99 and 4.31 (n = 6) for the determination of 3.0 × 10−4 mol L−1 PCM and VAN, respectively. It was also shown that the CL methods can measure PCM and VAN concentrations in various real samples. |
| Databáze: | OpenAIRE |
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