The synthesis and the magnetic properties of perfluoroalkyl organometallic chromium(III) complexes containing n-substituted salicylaldimines and other ligands

Autor:	R.M. Sheahan, B.O. West, Keith S. Murray, A.M. Van Den Bergen
Rok vydání:	1975
Předmět:	Denticity Magnetic moment Organic Chemistry Inorganic chemistry chemistry.chemical_element Biochemistry Inorganic Chemistry Chromium chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Molecular orbital Physical and Theoretical Chemistry Acetonitrile
Zdroj:	Journal of Organometallic Chemistry. 90:299-307
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)88123-1
Popis:	Perfluoroalkyl derivatives of CrIII containing tetradentate or bidentate ligands derived from N-substituted salicylaldimines have been prepared by the reaction between the ligands and dihaloperfluoroalkylchromium acetonitrile complexes. The compounds show considerable solid-state and solution stability. Their magnetic moments are all greater than the spin-only value for a d3 system, and a molecular orbital bonding scheme is suggested to explain this observation.
Databáze:	OpenAIRE
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