The behaviour of chlorofluoroethanes on β-aluminium(III) fluoride: a [] radiotracer study

Autor:	Erhard Kemnitz, Graeme D Tate, Tomaž Skapin, Hamid Bozorgzadeh, Mahmood Nickkho-Amiry, John M. Winfield
Rok vydání:	2001
Předmět:	Organic Chemistry Inorganic chemistry Chlorine-36 chemistry.chemical_element Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Aluminium Intramolecular force Environmental Chemistry Physical and Theoretical Chemistry Chlorofluoroethanes Fluoride Isomerization
Zdroj:	Journal of Fluorine Chemistry. 112:225-232
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(01)00527-9
Popis:	A [ 36 Cl ] radiotracer study of the behaviour of 1,1,2-trichlorotrifluoroethane on β-aluminium(III) fluoride at elevated temperature indicates that the isomerisation of CCl2FCClF2 to CCl3CF3 occurs by an intramolecular process. Isomerisation is followed by dismutation of CCl3CF3 to give CCl2FCF3 and CCl3CClF2. In neither reaction, surface Al–Cl groups are formed. The compound CCl3CClF2 undergoes further reaction, readily, apparently also via dismutation processes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::556d83ffbb45ec577a5b11706e32df6c https://doi.org/10.1016/s0022-1139(01)00527-9 Zobrazit plný text záznamu Full Text from ScienceDirect