Exploring opportunities for tuning phenyltris(pyrazol-1-yl)borate donation by varying the extent of phenyl substituent fluorination
Autor: | Paul J. Fischer, Charley B. Roe, Jasmine N. Stephenson, Rachel J. Dunscomb, Camille L. Carthy, Chip Nataro, Victor G. Young |
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Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Dalton Transactions. 52:5606-5615 |
ISSN: | 1477-9234 1477-9226 |
Popis: | Complexes of 3,4,5-trifluorophenyl- and 3,5-bis(trifluoromethyl)phenyltris(pyrazol-1-yl)borates have been prepared for comparison to pentafluorophenyl analogues to assess if donor modulation at κ3-N,N,N bound metals is feasible via this strategy. |
Databáze: | OpenAIRE |
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