Exploring opportunities for tuning phenyltris(pyrazol-1-yl)borate donation by varying the extent of phenyl substituent fluorination

Autor:	Paul J. Fischer, Charley B. Roe, Jasmine N. Stephenson, Rachel J. Dunscomb, Camille L. Carthy, Chip Nataro, Victor G. Young
Rok vydání:	2023
Předmět:	Inorganic Chemistry
Zdroj:	Dalton Transactions. 52:5606-5615
ISSN:	1477-9234 1477-9226
Popis:	Complexes of 3,4,5-trifluorophenyl- and 3,5-bis(trifluoromethyl)phenyltris(pyrazol-1-yl)borates have been prepared for comparison to pentafluorophenyl analogues to assess if donor modulation at κ3-N,N,N bound metals is feasible via this strategy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5547e22e9745e52d7f5492d030361e20 https://doi.org/10.1039/d3dt00735a Zobrazit plný text záznamu