Study of the photolysis of arenetricarbonylchromium complexes by IR, UV and 1H and 13C NMR spectroscopy

Autor:	V.N. Trembovler, V. N. Setkina, A. Ya. Shteinshneider, E.A. Domogatskaya, B.M. Yavorskii, N. K. Baranetskaya, Pavel V. Petrovskii
Rok vydání:	1983
Předmět:	Inorganic Chemistry chemistry.chemical_compound 13c nmr spectroscopy Chemistry Organic Chemistry Photodissociation Materials Chemistry Physical and Theoretical Chemistry Photochemistry Biochemistry Chromium hexacarbonyl
Zdroj:	Journal of Organometallic Chemistry. 248:161-169
ISSN:	0022-328X
Popis:	The mechanism of photolysis of arenetricarbonylchromium complexes is investigated by a number of spectral techniques. Experimental data are obtained in favour of the formation during the ArCr(CO) 3 photolysis of a multicenter complex, photodecay of which leads to the formation of chromium hexacarbonyl. A mechanism for the photolysis of arenetricarbonylchromium complexes is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::53777533171985b9b5a8ed60be6a33b4 https://doi.org/10.1016/0022-328x(83)85022-0 Zobrazit plný text záznamu