η3−η5 Interconversion vs Weak Bonding Interactions in Neutral Molybdenum(II) Complexes

Autor:	Vedavati G. Puranik, Amitabha Sarkar, Sanjoy K. Chowdhury, Uttamkumar Samanta
Rok vydání:	1997
Předmět:	Inorganic Chemistry Crystallography chemistry Molybdenum Stereochemistry Organic Chemistry chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Conjugated system Nmr data
Zdroj:	Organometallics. 16:2618-2622
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om9609269
Popis:	In a set of structurally related Mo(II) π-allyl complexes with a conjugated double bond appended to the allyl group, a weak bonding interaction such as B−H−Mo or C−H−Mo appears to prevent η3 to η5 interconversion. Structural assignments are made on the basis of NMR data, and crystal structure solutions are carried out for two of the complexes.
Databáze:	OpenAIRE
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