Alkylaluminum Complexes as Precatalysts in Hydroboration of Nitriles and Carbodiimides

Autor: Herbert W. Roesky, Yi Ding, Xiaoli Ma, Yashuai Liu, Wenqing Liu, Zhi Yang
Rok vydání: 2019
Předmět:
Zdroj: Organometallics. 38:3092-3097
ISSN: 1520-6041
0276-7333
DOI: 10.1021/acs.organomet.9b00421
Popis: The metathesis reaction of aluminum(III) dihydride LAlH2 (1) (L = (ArNCMe)2CH, Ar = 2,6-i-Pr2C6H4) with n-BuLi and n-Bu2Mg, respectively, resulted in di-n-butyl aluminum complex LAl(n-Bu)2 (2). Mea...
Databáze: OpenAIRE