An ESR study on the reaction between dicarbonyl titanocene and aryl-tin halides

Autor:	Ji-Tao Wang, Zhi-De Zhang, Ling-Jun Bai
Rok vydání:	1996
Předmět:	Chemistry Aryl Halide chemistry.chemical_element General Chemistry Resonance (chemistry) Photochemistry Medicinal chemistry Esr spectra Elimination reaction Paramagnetism chemistry.chemical_compound Spectroscopy Tin
Zdroj:	Heteroatom Chemistry. 7:119-122
ISSN:	1098-1071 1042-7163
DOI:	10.1002/(sici)1098-1071(199603)7:2<119::aid-hc3>3.0.co;2-8
Popis:	The oxidation elimination reaction between dicarbonyl titanocene and aryltin halides was studied by means of paramagnetic resonance spectroscopy. The radical intermediates containing Ti(III) were discovered from the ESR spectra to be (Cp2TiSnArnX3-n), Cp2Ti(CO)X, and Cp2TiX, and a radical mechanism for the reaction is proposed. © 1996 John Wiley & Sons, Inc.
Databáze:	OpenAIRE
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