COPOLYMERIZATION STUDY OF 4-VINYLPYRIDINE WITH N -DODECYLACRYLAMIDE
| Autor: | Alain Brembilla, Lucien Lalloz, Christine Damas, Pierre Lochon, Robert Clément |
|---|---|
| Rok vydání: | 1997 |
| Předmět: |
Polymers and Plastics
Chemistry Organic Chemistry General Physics and Astronomy Triad (anatomy) Carbon-13 NMR Mass spectrometry Resonance (chemistry) medicine.anatomical_structure Elemental analysis Polymer chemistry Materials Chemistry Copolymer medicine Reactivity (chemistry) Amphiphilic copolymer |
| Zdroj: | European Polymer Journal. 33:1099-1103 |
| ISSN: | 0014-3057 |
| Popis: | Random copolymers of 4-vinylpyridine and N -dodecylacrylamide were synthesized by low conversion bulk free radical copolymerization using 2,2′-azobisisobutyronitrile as initiator. Copolymer compositions were obtained from NMR spectrometry and elemental analysis. The reactivity ratios r VP and r C 12 AM as determined from the Fineman-Ross, Kelen-Tudos and Mayo-Lewis methods were found to be 4.13 and 0.27, respectively. The examination of the C-4 resonance peak in 13 C NMR data reveals a triad effect. A good agreement was observed for the experimental triads fractions determination and their calculation from r VP and r C12 . © 1997 Elsevier Science Ltd |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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