π-Back-Bonding in Bis(isonitrile) Complexes of Rhodium(II) Acetate: Structural Analogs for Rhodium Carbenoids

Autor:	Cassandra T. Eagle, Carl U. Pfaff, David G. Farrar, Julian A. Davies, Lee Miller, Constance Kluwe
Rok vydání:	1998
Předmět:	Inorganic Chemistry chemistry.chemical_compound Rhodium(II) acetate Chemistry Organic Chemistry Polymer chemistry Organic chemistry chemistry.chemical_element Physical and Theoretical Chemistry Pi backbonding Rhodium
Zdroj:	Organometallics. 17:4523-4526
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om980066r
Popis:	Rh2(O2CCH3)4·2C⋮NC6H4R (R = (CH3)2N−(1), −H (2), −CF3 (3)) were synthesized and characterized by X-ray crystallography. The structures exhibited several common features: (i) a relatively short Rh−...
Databáze:	OpenAIRE
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