ChemInform Abstract: Preparation of Mn(C6F5)2 Compounds by Treatment of Hg(C6F5)2 with Manganese Metal - A Novel Synthesis of d-Block Organometallics

Autor:	Bruce O. West, Jozef L. Latten, Ronald Stanley Dickson, Glen B. Deacon
Rok vydání:	2010
Předmět:	Metal chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Mass spectrum chemistry.chemical_element General Medicine Manganese Block (periodic table) Toluene Mercury (element) Nuclear chemistry
Zdroj:	ChemInform. 24
ISSN:	0931-7597
DOI:	10.1002/chin.199327256
Popis:	Prolonged reaction of manganese metal with bis(pentafluorophenyl)mercury in thf or 1,2-dimethoxyethane (dme) yields Mn(C 6 F 5 ) 2 (thf) 2 or Mn(C 6 F 5 ) 2 (dme). The latter reacts with N,N,N′,N′-tetramethylethane-1,2-diamine(tmen) in toluene to give Mn(C 6 F 5 ) 2 (tmen). Mass spectra indicate the complexes have associated structures. Impure Mn( p -HC 6 F 4 ) 2 (dme) was obtained from manganese metal and Hg( p -HC 6 F 4 ) 2 .
Databáze:	OpenAIRE
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