Fluoride Counterion Boosts Gold(I) Catalysis: Case Studies for Hydrodefluorination and CO2 Hydrosilylation

Autor: Yuhang Yao, Jiyun Hu, Guiyu Liu, Yin-Shan Meng, Song Gao, Jun-Long Zhang
Rok vydání: 2023
Předmět:
Zdroj: Inorganic Chemistry Frontiers.
ISSN: 2052-1553
DOI: 10.1039/d3qi00452j
Popis: We reported herein a novel gold(I) bifluoride complex, LAuHF2, supported by a sterically bulky ligand (L, tBuXantphos), displays exceptional reactivity toward hydrodefluorination (HDF) and hydrosilylation of CO2 in the presence...
Databáze: OpenAIRE