The role of the excited states in the photochemical behavior of ruthenocene in halocarbon solvents

Autor:	S. Sostero, Orazio Traverso, G. A. Mazzocchin
Rok vydání:	1974
Předmět:	Inorganic Chemistry Solvent chemistry.chemical_compound Electron transfer chemistry Excited state Thermal decomposition Materials Chemistry Ruthenocene Halocarbon Irradiation Physical and Theoretical Chemistry Photochemistry
Zdroj:	Inorganica Chimica Acta. 11:237-241
ISSN:	0020-1693
Popis:	Halocarbon solvents appears to form charge-transfer complexes with ruthenocene. Ruthenocene in halo-carbon solvents exibits a new band of electron transfer to solvent type at 285 nm. Irradiation by light, which excites the complexes and not the components, caused the oxidation of ruthenocene to ruthenicenium cation. A possible mechanism of the thermal decomposition of the ruthenicenium cation is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4c54a89cf000ecb0f97cb4fee43aa7e1 https://doi.org/10.1016/s0020-1693(00)93715-0 Zobrazit plný text záznamu