ChemInform Abstract: Pd/C-Catalyzed Carbonylative Esterification of Aryl Halides with Alcohols by Using Oxiranes as CO Sources

Autor:	Dong-Su Kim, Chul‐Ho Jun, Byul Hana Min, Hyo Soon Park
Rok vydání:	2016
Předmět:	inorganic chemicals Phthalimides chemistry.chemical_compound chemistry Aryl Intramolecular force Organic chemistry Halide General Medicine Esterification reaction Carbonylation Carbon monoxide Catalysis
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201636077
Popis:	A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway. Intramolecular versions of this process serve as methods for the synthesis of lactones and phthalimides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4c4e000e8441f3f1fa51816e5024f84e https://doi.org/10.1002/chin.201636077 Zobrazit plný text záznamu Plný text