Exploiting the reactivity of actinide fluoride bonds for the synthesis and characterization of a new class of monometallic bis(azide) uranium complexes
| Autor: | Alejandro G. Lichtscheidl, David E. Morris, Karla A. Erickson, Marisa J. Monreal, Andrew T. Nelson, Jaqueline L. Kiplinger, Brian L. Scott |
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| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Ligand Organic Chemistry 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry Toluene 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound chemistry Oxidation state visual_art X-ray crystallography Materials Chemistry visual_art.visual_art_medium Reactivity (chemistry) Azide Physical and Theoretical Chemistry Fluoride Nuclear chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 857:180-186 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2017.10.044 |
| Popis: | The terminal actinide fluoride bonds in (C 5 Me 5 ) 2 ThF 2 (py) (py = pyridine) and (C 5 Me 5 ) 2 UF 2 (O=PR 3 ) (R = Me, Ph) react with two equivalents of Me 3 SiN 3 in toluene to form the polymeric thorium bis(azide), [(C 5 Me 5 ) 2 Th(N 3 ) 2 ] ∞ , and a new class of monometallic uranium bis(azide) complexes, (C 5 Me 5 ) 2 U(N 3 ) 2 (O=PR 3 ), respectively. Full characterization of the novel complexes (C 5 Me 5 ) 2 ThF 2 (py) and (C 5 Me 5 ) 2 UF 2 (O=PR 3 ) are reported, including the solid-state structures of (C 5 Me 5 ) 2 ThF 2 (py) and (C 5 Me 5 ) 2 U(N 3 ) 2 (O=PPh 3 ). Electronic absorption spectral data are also reported for (C 5 Me 5 ) 2 AnF 2 (py) (An = Th, U) and (C 5 Me 5 ) 2 U(N 3 ) 2 (O=PR 3 ) to confirm metal oxidation state and enable elucidation of the fluoride and azide ligand bonding in these complexes. |
| Databáze: | OpenAIRE |
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