Dihalo pentafluorophenyl tetrahydrothiophen gold(III) complexes, their preparation and reactions
Autor: | B. Bergareche, Antonio Laguna, Rafael Usón |
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Rok vydání: | 1980 |
Předmět: | |
Zdroj: | Journal of Organometallic Chemistry. 184:411-416 |
ISSN: | 0022-328X |
DOI: | 10.1016/s0022-328x(00)93767-7 |
Popis: | The complex Au(C 6 F 5 )(tht) undergoes oxidative addition when treated in solution with halogens, to give Au(C 6 F 5 )X 2 (tht) (X = Cl, Br or I). The tetrahydrothiophen ligand of the latter can be displaced by neutral or anionic ligands to give, respectively, the neutral complexes Au(C 6 F 5 )X 2 L (L = Group IVB, VB or VIB ligand) or the anionic complexes [Au(C 6 F 5 )X 2 X′] - (X′ = Cl or SCN). |
Databáze: | OpenAIRE |
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