Functionalizing Fullerenes Through Cycloaddition Reactions

Autor:	Ripudaman Malhotra, Apparao Satyam, Tilak Bhardawaj, Asutosh Nigam, Subhash C. Narang, Susanna Ventura, Donald C. Lorents, Sivapackia Ganapathiappan
Rok vydání:	1992
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Fullerene Materials science chemistry Computational chemistry Sulfur trioxide Cyclohexanone Infrared spectroscopy Maleic anhydride Cycloaddition Adduct Nitrone
Zdroj:	MRS Proceedings. 247
ISSN:	1946-4274 0272-9172
DOI:	10.1557/proc-247-301
Popis:	We have explored several cycloaddition reactions as a general approach for preparing fullerene derivatives. In view of their electron-deficient nature, they are expected to participate as dienophiles rather than dienes in cycloadditions. This behavior is exemplified in their reactions with sulfur trioxide, diphenylisobenzofuran, and the nitrone from cyclohexanone and N-methyl-hydroxylamine. Fullerenes also formed adducts with maleic anhydride, although in this case the nature of the adduct is not clear. While changes in physical properties such as solubility or IR spectra clearly indicated formation of adducts, mass spectral analysis of diese and many other fullerene derivatives often showed ions due to fullerenes; thus confirmatory evidence for the derivatives was not available from mass spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::48207e67a2c937d69c289b70cfb90435 https://doi.org/10.1557/proc-247-301 Zobrazit plný text záznamu Full text from SpringerLink