Additional reactions of silane with ethylene or acetylene in the gas phase on metal oxides

Autor:	Kenji Iwata, Masahiko Mitsuzuka, Masayoshi Itoh
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Ethylene chemistry Acetylene Hydrosilylation Process Chemistry and Technology Dehydrogenation Photochemistry Vinylsilane Silane Catalysis Coupling reaction
Zdroj:	Applied Catalysis A: General. 217:185-189
ISSN:	0926-860X
DOI:	10.1016/s0926-860x(01)00609-3
Popis:	In the reaction of silane with acetylene, MgO catalyzed the dehydrogenative coupling reaction to give ethynylsilane selectively, and ZrO 2 and SiO 2 -Al 2 O 3 catalyzed the hydrosilylation reaction to give vinylsilane. ZrO 2 showed high catalytic activity in the hydrosilylation reaction between silane and ethylene to produce ethylsilane. The acid and base properties of the oxides determined the selectivities of the reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47fecd1e91e5ab383305ff51177c0308 https://doi.org/10.1016/s0926-860x(01)00609-3 Zobrazit plný text záznamu Full Text from ScienceDirect