Hydrogenolysis of carbonchlorine bonds in carbon tetrachloride and trichlorofluoromethane in the presence of catalytic quantities of tris(triphenylphosphine) ruthenium(II) dichloride
| Autor: | Emil M. Georgiev, Koljo Troev, Shaofeng Xie, D. Max Roundhill |
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| Rok vydání: | 1994 |
| Předmět: |
Chloroform
Trichlorofluoromethane Organic Chemistry chemistry.chemical_element Homogeneous catalysis Biochemistry Medicinal chemistry Ruthenium Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Hydrogenolysis Materials Chemistry Carbon tetrachloride Organic chemistry Physical and Theoretical Chemistry Triphenylphosphine |
| Zdroj: | Journal of Organometallic Chemistry. 482:39-44 |
| ISSN: | 0022-328X |
| Popis: | The hydrogenolysis of carbon tetrachloride to chloroform, and of trichlorofluoromethane to hydrodichlorofluoromethane, are catalysed by the complexes RuCl 2 (PPh 3 ) 3 and RuCl 2 (dppe) 2 . The conversion of carbon tetrachloride into chloroform is more complete than the conversion of trichlorofluoromethane into hydrodichlorofluoromethane. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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