Synthesis and Properties of Polymerization-Filled Composites Based on Polypropylene and Single-Wall Carbon Nanotubes
| Autor: | T. V. Monakhova, P. M. Nedorezova, V. G. Shevchenko, A. A. Arbuzov, O. M. Palaznik, Vadim G. Krasheninnikov |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Polypropylene
Filler (packaging) Materials science Polymers and Plastics Composite number chemistry.chemical_element 02 engineering and technology Carbon nanotube 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention chemistry.chemical_compound chemistry Polymerization law Specific surface area Materials Chemistry Ceramics and Composites Thermal stability Composite material 0210 nano-technology Carbon |
| Zdroj: | Polymer Science, Series B. 63:161-174 |
| ISSN: | 1555-6123 1560-0904 |
| DOI: | 10.1134/s1560090421020093 |
| Popis: | Composites based on polypropylene and single-wall carbon oxygen-containing nanotubes with a specific surface area of 360 and 500 m2/g are synthesized in the medium of liquid propylene using the catalytic system rac-Me2Si(2-Me-4-PhInd)2ZrCl2/МАО. Optimum polymerization conditions ensuring a fairly high rate of the process are determined, and the composites with the filler content in the range from 0.3 to 13.0 wt % are obtained. It is shown that the presence of functional groups enhances the filler agglomeration tendency during composite formation. Effects of the type of carbon nanofiller on the thermal stability, thermo-oxidative resistance, and thermal and electrophysical characteristics of the composites are studied. It is found that the filler inhibits the processes of oxidation and destruction of polypropylene crystallites. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink