FTIR matrix isolation study of uridine, thymidine, ribose, and glucose

Autor:	Vladislav Izvekov, G.G. Sheina, S. A. Krasnokutski, Yu. P. Blagoi, A. Yu. Ivanov
Rok vydání:	1999
Předmět:	Stereochemistry Organic Chemistry Thermal decomposition Matrix isolation Uridine Analytical Chemistry Inorganic Chemistry Ftir spectra chemistry.chemical_compound chemistry Intramolecular force Ribose Fourier transform infrared spectroscopy Thymidine Spectroscopy
Zdroj:	Journal of Molecular Structure. :249-252
ISSN:	0022-2860
DOI:	10.1016/s0022-2860(98)00665-6
Popis:	FTIR spectra of uridine, thymidine, ribose, 2-deoxyribose and glucose were measured in the range of 4000–450 cm −1 in the low-temperature Ar and Ne matrices. The experimental conditions were optimized to exclude the thermal decomposition of these unstable compounds. The spectral manifestations of conformations of sugars stabilized by intramolecular H-bonds were detected. It was shown that the syn-conformations of uridine and thymidine were stabilized by intramolecular H-bond O 5′ H…O 2 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46d69f19345e7b0b1112dd9a215b8080 https://doi.org/10.1016/s0022-2860(98)00665-6 Zobrazit plný text záznamu Full Text from ScienceDirect