ChemInform Abstract: Red-Al® Reduction of 4-Silyloxy Propargylic Alcohols. A Surprising Round Trip for the Silyl Group

Autor:	Roumen Nikolaev Radinov, Errol Sheldon Schnurman
Rok vydání:	2010
Předmět:	Reduction (complexity) Allylic rearrangement Stereospecificity chemistry Silylation Group (periodic table) chemistry.chemical_element General Medicine Oxygen Carbon Medicinal chemistry
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199911081
Popis:	The Red-Al ® reduction of 4-silyloxy propargylic alcohols to 4-silyloxy allylic alcohols involves two consecutive regio- and stereospecific 1,3 silyl migrations — from oxygen to carbon and then back to the original oxygen.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46a2fef48f365617c7304a150f3b7ab0 https://doi.org/10.1002/chin.199911081 Zobrazit plný text záznamu Plný text