Carbon-carbon bond formation at dinuclear metal centres

Autor:	A. G. Orpen, Robert Edgar Colborn, Peter Woodward, Kirsty A. Macpherson, J. Roue, Kevin A. Mead, Andrew F. Dyke, Selby A. R. Knox
Rok vydání:	1982
Předmět:	chemistry.chemical_classification Olefin fiber Transition metal carbene complex Carbyne Alkyne Metal chemistry.chemical_compound chemistry Carbon–carbon bond visual_art Polymer chemistry visual_art.visual_art_medium Carbene Alkyl
Zdroj:	Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences. 308:67-73
ISSN:	2054-0272 0080-4614
DOI:	10.1098/rsta.1982.0147
Popis:	The Fischer-Tropsch synthesis of hydrocarbons probably involves an array of carbon-carbon bond-formation processes occurring to unite carbene, carbyne, alkyl, olefin, and related species on a metal surface. In seeking to understand the nature of such processes, model diruthenium complexes have been prepared and the products of their thermolysis and reactions with unsaturated hydrocarbons investigated. The combination at a diruthenium centre of two carbenes, of a carbene and an alkyne, and of a carbyne and an olefin is described, and the possible implications for metal surface processes are emphasized.
Databáze:	OpenAIRE
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