Effect of the polarity of the medium on the ionic radiation-induced polymerization of elemental (white) phosphorus

Autor:	Natalia Tarasova, V. I. Ermakov, I. A. Lavrov, Yu. V. Smetannikov, M. A. Sinaiskii, I.M. Artemkina
Rok vydání:	2006
Předmět:	chemistry.chemical_classification White Phosphorus Phosphorus Inorganic chemistry chemistry.chemical_element Ionic bonding General Chemistry Polymer Sulfur Hexane chemistry.chemical_compound chemistry Polymerization Benzene
Zdroj:	Doklady Chemistry. 410:189-191
ISSN:	1608-3113 0012-5008
DOI:	10.1134/s0012500806100077
Popis:	In recent years, inorganic polymers (red phosphorus, polymeric sulfur and arsenic, compositions based on them, etc.) have been the objects of intensive theoretical and applied studies [1, 2] because elucidation of fundamental characteristics would help to identify the optimal ways of synthesis of these polymers and would contribute to the solution of the general problem of the molecular structure‐inorganic material structure‐material physicochemical properties relationship. Within the framework of the research topic of radiation-induced chemical synthesis of inorganic phosphorus polymers and materials with specified properties based on them, we studied the radiation-induced polymerization of white phosphorus in nonpolar media (benzene, halohydrocarbons, and hexane) [3]. The process was shown to follow a radical mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4417c6298874a4a4346e5b36e3b33342 https://doi.org/10.1134/s0012500806100077 Zobrazit plný text záznamu Full text from SpringerLink