Search for chemiluminescence from tert-butyl 9-fluorenyl peroxide and 9-fluorenyl hydroperoxide

Autor:	Lei Zhang, G. David Mendenhall
Rok vydání:	1997
Předmět:	Organic peroxide Reaction mechanism General Chemical Engineering Radical Thermal decomposition General Physics and Astronomy General Chemistry Photochemistry Peroxide law.invention chemistry.chemical_compound Benzonitrile chemistry Decalin law Chemiluminescence
Zdroj:	Journal of Photochemistry and Photobiology A: Chemistry. 107:169-173
ISSN:	1010-6030
DOI:	10.1016/s1010-6030(96)04588-1
Popis:	Thermolysis of solutions of 9-fluorenyl tert-butyl peroxide (BOOF; decalin, 137–162°C, log k s = 14.28 ± 0.02 − (144.2 ± 2 kJ )/θ ) or 9-fluorenyl hydroperoxide (FOOH; benzonitrile, 152 °C) did not give detectable chemiluminescence. In contrast, the induced decomposition of 9-fluorenyl hydroperoxide with tert-butoxyl radicals at room temperature was highly chemiluminescent. The different behavior was ascribed to the decreased fluorescence of 9-fluorenone at elevated temperatures. Solutions of tert-butyl diphenylmethyl peroxide (152°C) were weakly chemiluminescent in the presence of a fluorescence sensitizer. The photolysis and base-induced decompositions of BOOF were studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::433727770948c30af3de790a7341bb2e https://doi.org/10.1016/s1010-6030(96)04588-1 Zobrazit plný text záznamu Full Text from ScienceDirect