Pure Co films of low resistivity and high conformality by low temperature thermal CVD/ALD using novel Co precursors

Autor: Ivan Oschchepkov, Changhee Ko, Raphael Rochat
Rok vydání: 2017
Předmět:
Zdroj: 2017 IEEE International Interconnect Technology Conference (IITC).
DOI: 10.1109/iitc-amc.2017.7968940
Popis: A new family of highly volatile alkylsilyl-functionality Co precursors, R 3 SiCo(CO) 4 , has been synthesized. One of them, Et 3 SiCo(CO) 4 , has been evaluated by low temperature thermal chemical vapor deposition (CVD) and atomic layer deposition (ALD), which gave low resistive (29 μΩ·cm) pure Co films with a good step overage. Dynamic stability test of Et 3 SiCo(CO) 4 also exhibited a better stability at 40°C and 50°C, compared to CCTBA, a conventional Co precursor.
Databáze: OpenAIRE