Ion Conductivity and Vibrational Spectra of LiNO3–KNO3 + Al2O3 Composites
| Autor: | M. M. Gafurov, A. M. Amirov, Z. Yu. Kubataev, K. Sh. Rabadanov, M. B. Ataev, N. S. Shabanov, M. A. Akhmedov |
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| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
Materials science Lithium nitrate Doping technology industry and agriculture 02 engineering and technology Conductivity 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Dielectric spectroscopy chemistry.chemical_compound symbols.namesake chemistry Phase (matter) Electrochemistry Fast ion conductor symbols Composite material 0210 nano-technology Raman spectroscopy Eutectic system |
| Zdroj: | Russian Journal of Electrochemistry. 55:573-578 |
| ISSN: | 1608-3342 1023-1935 |
| Popis: | Composite solid electrolytes are synthesized on the basis of the eutectic nitrate mixture of 0.42LiNO3–0.58KNO3 doped by aluminum oxide nanosized powder. The impedance spectroscopy technique is used to study the conductivity of the obtained composites. Heterogeneous doping results in an increase in ion conductivity and a decrease in activation energy. The method of Raman spectroscopy shows that the doping by aluminum oxide leads to formation of an amorphous phase. At low nanopowder concentrations, amorphization is brought about by the lithium nitrate phase. |
| Databáze: | OpenAIRE |
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