Highly active homoleptic nickel(II) bis-N-heterocyclic carbene catalyst for Suzuki–Miyaura and Heck cross-coupling reactions
| Autor: | Moulali Vaddamanu, Prabusankar Ganesan, Ramesh Karupnaswamy, Muthukumaran Nirmala, Sathyanarayana Arruri, Maruthupandi Mannarsamy, Mannem Adinarayana |
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| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Substrate (chemistry) chemistry.chemical_element 010402 general chemistry 01 natural sciences Coupling reaction 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound Nickel chemistry Heck reaction Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Homoleptic Carbene |
| Zdroj: | Polyhedron. 158:125-134 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2018.10.028 |
| Popis: | New homoleptic nickel(II) biscarbene complex was synthesized and structurally characterized. The complex depicted the excellent catalytic activities with only 3 mol% catalyst loading along with wide substrate scope for the Suzuki–Miyaura cross-coupling reactions (twenty six examples) and Heck coupling reactions (eighteen examples). |
| Databáze: | OpenAIRE |
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