Nanoporous Polymer Networks of N-Vinylpyrrolidone with Triethylene Glycol Dimethacrylate and Sorption of Macromolecules
| Autor: | N. V. Fadeeva, A. A. Grishchuk, E. I. Knerel’man, Svetlana V. Kurmaz, G. I. Davydova |
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| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Polyvinylpyrrolidone Nanoporous 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Adsorption chemistry Chemical engineering Desorption Materials Chemistry Copolymer medicine Polystyrene 0210 nano-technology Triethylene glycol medicine.drug |
| Zdroj: | Polymer Science, Series A. 61:186-193 |
| ISSN: | 1555-6107 0965-545X |
| DOI: | 10.1134/s0965545x19020068 |
| Popis: | Nanoporous polymer networks with different composition are obtained by the 3D radical copolymerization of N-vinylpyrrolidone and triethylene glycol dimethacrylate in the presence of a branched copolymer that acts as a macromolecular template and a pore-forming agent. The processes of adsorption of polyvinylpyrrolidone, poly(methyl methacrylate), and polystyrene from their mixtures in chloroform by the N‑vinylpyrrolidone-based nanoporous polymer network and their desorption are studied. The molecular-weight distribution and composition of PVP–PMMA and PVP–PS mixtures (before and after adsorption) and macroobjects (after desorption) are studied by GPC and IR spectroscopy. A high selectivity of the nanoporous polymer network for the adsorption of polyvinylpyrrolidone from its mixture with nonpolar polystyrene is shown. |
| Databáze: | OpenAIRE |
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