Highly efficient phosphine-catalyzed routes to α-imidoacrylates and 2,3-diimidopropanoates

Autor:	Vladimir I. Galkin, Daut R. Islamov, Karim R. Islamov, Arthur F. Gubaev, Anton V. Il'in
Rok vydání:	2021
Předmět:	Phthalimide chemistry.chemical_compound chemistry Succinimide Methyl propiolate Atom economy Organic Chemistry Selectivity Combinatorial chemistry Vicinal Phosphine Catalysis
Zdroj:	Chemistry of Heterocyclic Compounds. 57:175-180
ISSN:	1573-8353 0009-3122
Popis:	The highly efficient α- and vicinal bis-addition of cyclic imides to methyl propiolate in high yields and β-addition of these imides to α-imidoacrylates in quantitative yields is reported. These reactions offer a simple metal-free method for a gram-scale preparation of practically useful α-imidoacrylates and vicinal bisimides under mild conditions with high atom economy and selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::403a33ada1f53d5a132d5663be67c859 https://doi.org/10.1007/s10593-021-02890-x Zobrazit plný text záznamu Plný text ve formátu PDF