Cyclodextrin-click-cucurbit[6]uril: Combi-Receptor for Supramolecular Polymer Systems in Water
| Autor: | Maricica Munteanu, Helmut Ritter, SooWhan Choi |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
chemistry.chemical_classification
Hydrodynamic radius Polymers and Plastics Cyclodextrin Organic Chemistry Supramolecular chemistry Combinatorial chemistry Inorganic Chemistry Supramolecular polymers chemistry Dynamic light scattering 1 3-Dipolar cycloaddition Materials Chemistry Click chemistry Proton NMR Organic chemistry |
| Zdroj: | Macromolecules. 42:3887-3891 |
| ISSN: | 1520-5835 0024-9297 |
| DOI: | 10.1021/ma900397m |
| Popis: | We describe the synthesis of a combi-receptor via the click reaction of 6I-azido-6I-deoxycyclomaltoheptaose onto (propargyl-O)6cucurbit[6]uril under microwave-assisted conditions. The process was investigated by 1H NMR, FT-IR spectroscopy, and MALDI-TOF mass spectrometry. The ability of the synthesized compound to act as a molecular receptor and supramolecular building block in combination with NIPAM- and adamantane-containing methacrylates was investigated by turbidity measurement and dynamic light scattering (DLS). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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