Medium-Sized Cyclophanes, 63.1 Synthesis and Structure of [2.2]Metacyclophane-1,2-Diol and Conversion Into [2.2]Metacyclophane-1,2-Dione by Swern Oxidation

Autor:	Tomoki Manabe, Tatsunori Saisyo, Toru Hironaka, Ken-ichiro Okuyama, Takehiko Yamato
Rok vydání:	2003
Předmět:	chemistry.chemical_compound chemistry 010405 organic chemistry Diol Swern oxidation Organic chemistry General Chemistry McMurry reaction 010402 general chemistry 01 natural sciences 0104 chemical sciences
Zdroj:	Journal of Chemical Research. 2003:63-65
ISSN:	2047-6507 1747-5198
DOI:	10.3184/030823403103173183
Popis:	McMurry cyclisation of 1,2-bis(5- t-butyl-2-methyl-3-formylphenyl)ethane 2 afforded anti-[2.2]metacyclophan-1-ene 3 and anti-[2.2]metacyclophane-1,2-diols 4, which were converted into the corresponding 1,2-dione 6 by Swern oxidation.
Databáze:	OpenAIRE
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