Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges †

Autor:	Hiroyuki Hosomi, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii, Satoshi Nishino, Yuzo Nishida
Rok vydání:	1999
Předmět:	chemistry.chemical_compound Cyclohexane Chemistry Polymer chemistry General Chemistry Hydrogen peroxide Photochemistry
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :1509-1514
ISSN:	1364-5447 0300-9246
DOI:	10.1039/a809725i
Popis:	Several dinuclear iron(III) complexes with µ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.
Databáze:	OpenAIRE
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