Complexation of europium(III) with 2,2′-dipyridyl in Eu(An)3-2,2′-dipyridyl ethyl acetate systems

Autor:	O. A. Varnavskaya, E. V. Yudina, T. G. Vovk, V. P. Smagin
Rok vydání:	2012
Předmět:	Materials Science (miscellaneous) Enthalpy Inorganic chemistry Ethyl acetate chemistry.chemical_element Ion Gibbs free energy Inorganic Chemistry symbols.namesake chemistry.chemical_compound chemistry symbols Physical and Theoretical Chemistry Europium
Zdroj:	Russian Journal of Inorganic Chemistry. 57:367-372
ISSN:	1531-8613 0036-0236
DOI:	10.1134/s003602361203031x
Popis:	Complexation of europium(III) with 2,2′-dipyridyl in Eu(An)3-2,2′-dipyridyl-ethyl acetate systems, where An is acetylacetonate, trichloroacetate, or trifluoroacetate ions, was studied by spectrophotometric methods. The stability constants of the complexes at different temperatures were determined, and Gibbs energy, enthalpy, and entropy changes in complexation were calculated. The influence of the initial organic ligands on complexation was elucidated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3dd844dea6e59cbd0f8a17e7f62030bd https://doi.org/10.1134/s003602361203031x Zobrazit plný text záznamu Full text from SpringerLink