Photocatalytic Aerobic Oxidation of Alkenes into Epoxides or Chlorohydrins Promoted by a Polymer-Supported Decatungstate Catalyst

Autor:	Yoichi M. A. Yamada, Alexandros Athanasoulis, Ioannis N. Lykakis, Yasuhiro Uozumi, Rikako Ishii, Theodoros S. Symeonidis
Rok vydání:	2017
Předmět:	Chlorohydrins 010405 organic chemistry Chemistry Organic Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Catalysis Solvent Matrix (chemical analysis) Polymer chemistry Photocatalysis Physical and Theoretical Chemistry Polymer supported
Zdroj:	ChemPhotoChem. 1:479-484
ISSN:	2367-0932
DOI:	10.1002/cptc.201700079
Popis:	An efficient photocatalytic method for the aerobic oxidation of alkenes to afford either the corresponding epoxides or chlorohydrins, depending on the solvent of choice, is presented. This effective approach uses a novel polymer-supported decatungstate catalyst bearing a poly(isopropylacrylamide alkylammonium) matrix and yields the corresponding products in moderate to excellent yields.
Databáze:	OpenAIRE
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