Predicting phase equilibria in one-component systems
| Autor: | M. R. Korchuganova, Z. N. Esina |
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| Rok vydání: | 2015 |
| Předmět: |
Similarity (geometry)
Chemistry Component (thermodynamics) Triple point Thermodynamics Enthalpy of vaporization Enthalpy of atomization symbols.namesake Phase (matter) symbols Physics::Atomic Physics Statistical physics Physics::Chemical Physics Physical and Theoretical Chemistry van der Waals force |
| Zdroj: | Russian Journal of Physical Chemistry A. 89:1135-1140 |
| ISSN: | 1531-863X 0036-0244 |
| DOI: | 10.1134/s0036024415070183 |
| Popis: | It is shown that Simon equation coefficients for n-alkanes and n-alcohols can be modeled using critical and triple point parameters. Predictions of the phase liquid-vapor, solid-vapor, and liquid-solid equilibria in one-component systems are based on the Clausius-Clapeyron relation, Van der Waals and Simon equations, and the principle of thermodynamic similarity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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