Ethyl acrylate copolymers as promising porogens for the synthesis of polydimethacrylates with controlled porous structures

Autor:	M. L. Bubnova, Svetlana V. Kurmaz, G. M. Bakova, I. S. Kochneva, E. I. Knerel’man, G. I. Davydova, E. O. Perepelitsina
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Materials science Polymers and Plastics Radical polymerization Polymer chemistry.chemical_compound Adsorption chemistry Specific surface area Polymer chemistry Materials Chemistry Copolymer Ethyl acrylate Porosity Triethylene glycol
Zdroj:	Polymer Science Series A. 55:712-720
ISSN:	1555-6107 0965-545X
DOI:	10.1134/s0965545x13120067
Popis:	The crosslinking radical polymerization of triethylene glycol dimethacrylate in bulk in the presence of 0–40 wt % ethyl acrylate-based copolymers of various compositions is studied, and some structuralphysical properties of the crosslinked polymers are investigated. The quantitative characteristics of their porous structures, such as the specific surface areas and the total pore volumes, are measured via the low-temperature adsorption of nitrogen. During sol-gel analysis, polymer additives are removed from network polymers with the use of benzene and pores with sizes from 4 to 500 nm occupy their places. The maximum specific surface area is approximately 17 m2/g. It is found that the specific surface area and total pore volume depend on the content of the polymer additive in the initial composition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b361fa3710290912819c55e644ead8d https://doi.org/10.1134/s0965545x13120067 Zobrazit plný text záznamu Full text from SpringerLink