The liquid crystal Click procedure for oligothiophene-tethered phthalocyanines – self-assembly, alignment and photocurrent

Autor:	Genya Uzurano, Matthias Lehmann, Akihiko Fujii, Masanori Ozaki, Moritz Dechant
Rok vydání:	2021
Předmět:	Photocurrent Materials science Fullerene Annealing (metallurgy) General Chemistry Photochemistry Amorphous solid chemistry.chemical_compound chemistry Liquid crystal Materials Chemistry Phthalocyanine Self-assembly Thin film
Zdroj:	Journal of Materials Chemistry C. 9:5689-5698
ISSN:	2050-7534 2050-7526
DOI:	10.1039/d1tc00710f
Popis:	A series of star-shaped liquid crystals (LCs) with a phthalocyanine donor core, oligothiophene antennae and fullerene acceptors have been successfully prepared. This hierarchical self-assembly results in a nanosegregated helical donor–acceptor–antennae LC-system promoted by the recently discovered Click procedure. This model system reveals all photophysical prerequisites for energy conversion, charge generation and transport. Uniform amorphous thin films of 150 nm could be produced by bar-coating. Annealing did not only induce the formation of columns via the Click procedure but also partially homeotropically aligned the non-clearing sample in a sandwich geometry (ITO and Ag/MoO3). This has been confirmed by microscopic studies and the measurement of photocurrent, which increased by a factor of 300 after the annealing step.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3a467ef63275168052c17d19053198f1 https://doi.org/10.1039/d1tc00710f Zobrazit plný text záznamu