Anodic oxidation of 5,10-dihydro-5,10-dimethylphenazine

Autor:	Donald W. Leedy, Ralph N. Adams, Robert F. Nelson, E. T. Seo
Rok vydání:	1966
Předmět:	Aqueous medium Anodic oxidation Clinical Biochemistry Inorganic chemistry General Medicine Electrochemistry Redox Combinatorial chemistry Analytical Chemistry chemistry.chemical_compound chemistry Nucleophile Propylene carbonate General Materials Science Acetonitrile Demethylation
Zdroj:	Fresenius' Zeitschrift für analytische Chemie. 224:184-196
ISSN:	0016-1152
DOI:	10.1007/bf00502648
Popis:	The compound 5,10-dihydro-5,10-dimethylphenazine (DMPZ) exhibits two succesive reversible, 1-electron oxidation-reduction steps in acetonitrile and propylene carbonate as solvents. This system has been tested by most of the known diagnostic criteria of electrochemical reversibility and found to adhere to all of them unambiguously. This model system provides a reference for comparison of other multi-stage electrochemical processes. When DMPZ is oxidized in solvents or additives which are strong nucleophiles demethylation accompanies the second stage of oxidation. Since this chemical follow-up reaction occurs in aqueous media it is of significance in the biological redox reactions of N-alkylated phenazines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::38764aba982d9e7ede70db5a5766f8ac https://doi.org/10.1007/bf00502648 Zobrazit plný text záznamu Full text from SpringerLink