One-Dimensional Array of Au Nanoparticles Fixed on Nanofibers of Organogelators by the Langmuir−Blodgett Method

Autor:	Hiroko Kawakami, Kazunori Toma, Tomoyuki Akutagawa, Ryo Tsunashima, Shin Ichiro Noro, Takayoshi Nakamura, Tomohiro Karasawa
Rok vydání:	2006
Předmět:	Materials science Stereochemistry Nanoparticle Crystal structure Langmuir–Blodgett film Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallinity Crystallography General Energy Nanofiber Monolayer Molecule Mica Physical and Theoretical Chemistry
Zdroj:	The Journal of Physical Chemistry C. 111:901-907
ISSN:	1932-7455 1932-7447
DOI:	10.1021/jp065061j
Popis:	The Langmuir−Blodgett (LB) method was applied to low molecular weight organogelator N-[N-(6-hydroxyhexyl)-3-carbamoylpropyl]-3,4,5-tris(dodecyloxy)benzamide (1) to form molecular-assembly fibers on a solid substrate. Molecule 1 formed a stable monolayer up to 40 mN/m at the air−water interface. The monolayer was transferred onto a mica surface at 35 mN/m. In the transferred film, fibrous structures with typical dimensions of 1.2 nm (height) × 50−100 nm (width) × 5−10 μm (length) were observed by atomic force microscopy. These structures were ordered in specific directions, reflecting the C6 surface crystal symmetry of mica. Lateral modulation frictional force microscope measurements revealed that the fibrous structures had high crystallinity and that the surface groups were hydrophilic. These results enabled us to construct functional fibers by introducing functional units into the hydrophilic part of molecule 1. N-[N-(6-Aminohexyl)-3-carbamoylpropyl]-3,4,5-tris(dodecyloxy)benzamide hydrochloride (2) has ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::375f0277066859cae822ec6b33e587e4 https://doi.org/10.1021/jp065061j Zobrazit plný text záznamu