Solvent Anions in Supercritical Carbon Dioxide: Formation of Complexes with Polar Solutes
| Autor: | Myran C. Sauer, I. A. Shkrob and |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
chemistry.chemical_classification
Supercritical carbon dioxide Chemistry Inorganic chemistry Halide Supercritical fluid Surfaces Coatings and Films Solvent chemistry.chemical_compound Carbon dioxide Materials Chemistry Organic chemistry Polar lipids (amino acids peptides and proteins) Physical and Theoretical Chemistry Alkyl |
| Zdroj: | The Journal of Physical Chemistry B. 105:7027-7032 |
| ISSN: | 1520-5207 1520-6106 |
| Popis: | It is shown that high-mobility multimer (CO2)n•- anions in supercritical (sc)-CO2 form stable complexes with water, aliphatic alcohols, alkyl halides, and alkyl nitriles. The complexation rate is 1... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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