Isomerization of 1-cyano-1-trimethylsiloxy-2-propene and its reactions with amines

Autor:	N. A. Keiko, Tatyana A. Kuznetsova, M. G. Voronkov, V. A. Pestunovich, E. O. Tsetlina, V. V. Keiko
Rok vydání:	1978
Předmět:	Propene Nickel chemistry.chemical_compound Colloid chemistry Polymer chemistry Pyridine Acrolein chemistry.chemical_element General Chemistry Isomerization Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:783-786
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925307
Popis:	1. Cyanosilylated acrolein and 2-ethoxyacrolein isomerize in the presence of secondary amines and react with an excess of the latter to form derivatives of propionamide and N-substituted aminosilanes. 2. Unlike 1-cyano-1-trimethylsiloxy-2-ethoxy-2-propene, 1-cyano-1-trimethylsiloxy-2-propene is thermally stable and does not isomerize under the action of the Speier catalyst, colloidal nickel, ZnI2, or pyridine.
Databáze:	OpenAIRE
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