Hollow Zeolites Encapsulating Ultra-Low Noble Metal Nanoparticles for HMF Oxidation

Autor:	Raj Ganesh S. Pala, V. Venkatesh, Dhyananand Yadaw, Kajal Tiwari, Sandeep Verma, Sri Sivakumar, Shilpi Saxena
Rok vydání:	2020
Předmět:	010405 organic chemistry chemistry.chemical_element Nanoparticle General Chemistry engineering.material 010402 general chemistry 01 natural sciences Catalysis Nanocapsules 0104 chemical sciences chemistry Colloidal gold engineering Noble metal Platinum Zeolite Palladium Nuclear chemistry
Zdroj:	Catalysis Letters. 151:921-931
ISSN:	1572-879X 1011-372X
DOI:	10.1007/s10562-020-03361-2
Popis:	We report the development of zeolite nanocapsules (MCM-22 and ZSM-5) encapsulating ultra-low amount (0.01 wt%) of noble metal nanoparticles (Gold, Platinum and Palladium) for the oxidation of HMF. These catalysts showed enhanced HMF conversion (> 95%) with higher yield (> 90%) of FDCA under mild conditions (60 °C, 0.3 MPa oxygen) in an organic solvent-free medium in 6 h. We also investigated the effect of size and amount of gold nanoparticles encapsulated inside zeolite capsules for the oxidation of HMF. We found that Au cluster loaded MCM-22 showed enhanced HMF conversion and yield of FDCA (91%).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::323a6c86225f516af9b0e7d219649702 https://doi.org/10.1007/s10562-020-03361-2 Zobrazit plný text záznamu Full text from SpringerLink