Experimental and theoretical studies on the bifurcated hydrogen bonded NLO active material of pure and crystal violet dye-doped L-argininium bis dihydrogen phosphate
| Autor: | D. Sajan, Lynnette Joseph, Reena Ittyachan, G. Vinitha, Jesby George, Ligi Cherian |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Photoluminescence Hydrogen bond Organic Chemistry Doping Crystal growth 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials Inorganic Chemistry Crystal chemistry.chemical_compound chemistry Molecule Physical chemistry Z-scan technique Crystal violet Electrical and Electronic Engineering Physical and Theoretical Chemistry 0210 nano-technology Spectroscopy |
| Zdroj: | Optical Materials. 92:111-124 |
| ISSN: | 0925-3467 |
| Popis: | Single crystals of pure and crystal violet dye-doped L-Argininium bis dihydrogen phosphate were grown using slow evaporation technique. The crystalline nature and the structure parameters were confirmed by powder X-ray diffraction technique. Blue and red shifting hydrogen bonds were predicted by DFT on the basis of vibrational spectral (FT-IR & FT-Raman), AIM and NBO analyses. Bifurcated N H⋯O and O H⋯O intermolecular hydrogen bonds in LADP molecule were visualized by Hirshfeld surface. 13C and 1H NMR spectroscopy confirmed the structure of LADP. Doped LADP crystal shows enhancements in the wavelength and longer lifetimes as identified from photoluminescence spectra and decay analysis respectively. The high values of electron mobility and low value of λelectron reflect the applicability of LADP in OLED devices. Enhancement in nonlinear optical parameters in dye-doped LADP crystal was revealed from the Z-scan technique which shows its usefulness in the fabrication of NLO devices. |
| Databáze: | OpenAIRE |
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